A systematic study has been carried out to quantify the effect of microcrystallite nucleation in the intrinsic layer of protocrystalline Si:H p-i-n solar cells prepared by rf plasma enhanced chemical vapor deposition (PECVD). Real-time spectroscopic ellipsometry (RTSE) results that have previously identified the transitions from amorphous to microcrystalline phase were confirmed with atomic force microscopy (AFM) images. The effects of the phase transitions in the bulk intrinsic layer, as well as near the p/i interface of p-i-n cells, have been evaluated as a function of film thickness and H2-dilution ratio (R=[H2]/[SiH4]). Illuminated and dark J-V characteristics are correlated with the microstructural evolution of the Si:H films yielding insight into the “sharpness” of the transition. Evidence of abrupt changes in the mobility gap is obtained from the selfconsistent numerical modeling of cell characteristics.
Pearce, J. (2019). The Role of Phase Transitions in Protocrystalline Si:H on the Performance their of Solar Cells. Afribary. Retrieved from https://tracking.afribary.com/works/the-role-of-phase-transitions-in-protocrystalline-si-h-on-the-performance-their-of-solar-cells
Pearce, Joshua "The Role of Phase Transitions in Protocrystalline Si:H on the Performance their of Solar Cells" Afribary. Afribary, 22 Apr. 2019, https://tracking.afribary.com/works/the-role-of-phase-transitions-in-protocrystalline-si-h-on-the-performance-their-of-solar-cells. Accessed 07 Nov. 2024.
Pearce, Joshua . "The Role of Phase Transitions in Protocrystalline Si:H on the Performance their of Solar Cells". Afribary, Afribary, 22 Apr. 2019. Web. 07 Nov. 2024. < https://tracking.afribary.com/works/the-role-of-phase-transitions-in-protocrystalline-si-h-on-the-performance-their-of-solar-cells >.
Pearce, Joshua . "The Role of Phase Transitions in Protocrystalline Si:H on the Performance their of Solar Cells" Afribary (2019). Accessed November 07, 2024. https://tracking.afribary.com/works/the-role-of-phase-transitions-in-protocrystalline-si-h-on-the-performance-their-of-solar-cells