ABSTRACT Concentrations of 16 priority polycyclic Aromatic Hydrocarbons (PAHs) were determined in 30 brands of Nigerian and imported pastas in Nigerian market. The pasta samples were categorised into (1) noodles (2) spaghetti and (3) macaroni. Analysis were performed by GC – MS after soxhlet extraction of the sample and clean up of the extract. The concentration of Σ16 PAHs in both the Nigerian and imported brands are in the range of 0.009 to 0.8 mgkg-1 and 0.002 to 0.007 mgkg-1 respectiv...
ABSTRACT The petroleum hydrocarbon composition of sediments from Qua Iboe River Estuary, Ibeno, South-Eastern Nigeria, was studied to determine the levels of these hydrocarbons in the marine environment. Ten sediment sites were sampled using a van veen Grab sampler. Chemical parameter, such as total organic carbon (TOC), was assessed using Blackey-walkey titration method. Soluble organic matter (SOM) was assessed using sohxlet extraction method and total petroleum hydrocarbon (TPH) was asses...
ABSTRACT The efficacy of silica obtained from our local sand as a carrier in synthesis of Nickel-Silica catalyst was investigated. Six samples of soil were collected from two different sites (comprising five white coloured samples collected from Iva valley, lower part of Milliken hill, namely: pottery 2 (P2), down iva (DI), run-off iva (ROI), pottery rock (POR), white chalk (WTC) and one brown coloured sample (UdS) collected from Udi Siding) in Enugu, Nigeria. Prior to treatment by flotation...
ABSTRACT The synthesis of ten new alkynylated derivatives of angular phenoxazine and alkynylated naphthoquinone was thoroughly investigated. The first intermediate, 6-chloro-5Hbenzo[a]phenoxazin-5-one was obtained by the condensation of 2-aminophenol with 2,3- dichloro-1,4- naphthoquinone in the presence of anhydrous sodium tricarbonate (IV) . Thereafter, the intermediate and 2,3-dichloro-1,4-naphthoquinone were each suggested to Sonogashira cross–coupling reaction under copper-, amine-, a...
ABSTRACT The Schiff base ligand, 2-[(E)-[{3--[(2-hydroxybenzylidene)amino]phenyl}imino)methyl]phenol was synthesized by condensing 1,3-diaminobenzene and 2-hydroxybenzaldehyde in absolute ethanol. Its Cr(III) and Cr(VI) complexes were equally synthesized. The ligand was characterized via UV, IR and NMR spectroscopy, whereas the complexes were characterized based on UV and IR spectroscopy and conductivity values. Stoichiometric studies indicated 1:1 metal to ligand ratio for both complexes. C...
ABSTRACT The azo-ligand, 1,5-dimethyl-2-phenyl-4-[(E)-(2,3,4-trihydroxylphenyl) diazenyl]- 1,2-dihydro-3H-pyrazol-3-one (H3L) and its Zn(II) and Cd(II) complexes have been synthesized and characterized based on stoichiometric, molar conductance, electronic and infra-red spectral studies. The results showed that H3L reacted with the metals in 2:1 ratio. H3L coordination was through the hydroxyl, azo and carbonyl groups to form [Zn(H2L)2] 2+ and [Cd(H2L)2] 2+ respectively. Solvent extraction s...
ABSTRACT The total alkaloid, tannins contents and antiulcer activity of the extracts from four selected medicinal plants were investigated. The total alkaloids content (TAC) was evaluated according to the chloride colometric method in which atropine was used as standard. While the total tannins content (TTC) was also determined using Folin Ciocalteau assay in which gallic acid was used as a standard. The antiulcer activity of the extracts was investigated using the ethanol induced model in w...
ABSTRACT The kinetics and mechanisms of the redox reactions of μ-oxo-bridged iron(III) complex ion Na4[(FeEDTA)2 O].12H2O denoted as Fe2 O4+, with the thiols-2-mercaptobenzothiazole(MBSH), 2- mercaptophenol(PhSH), 2-mercaptoacetic acid (MSH), and l-cysteine (RSH) have been investigated in aqueous perchloric acid medium at [H+]=1×10-4 mol dm-,3,I=0.05mol dm-3(NaClO4) and at T =27.0±0.1oC. The reactions were monitored under pseudo-first order condition .The rate of reaction was first-order i...
ABSTRACT Physicochemical and bacteriological analyses of underground water resources in Nkanu East and Nkanu West Local Government Areas of Enugu state, Nigeria were carried out to evaluate the potability and quality of the rural water supplies and to provide baseline data for future quality assessment. Underground water samples were collected from ten different boreholes in Nkanu East and Nkanu West LGAs. The parameters measured include temperature, colour, pH, electrical conductivity, turbi...
ABSTRACT Dyes from Pterocarpus osun Craib and Lawsonia inermis Linn. were extracted using ethanol and methanol respectively. The extracted dyes were subsequently purified using chromatographic methods. Purified pigments were characterized using Ultra-Violet Visible Spectrophotometer, Fourtier Transform Infrared Spectrophotometer and Lovibond Tintometer. The UV spectra of the dyes in petrol, kerosene and diesel showed presence of chromophores. The FTIR spectra of the dyes showed presence of ph...
ABSTRACT Five species of Mushroom namely Termitomyces robustus, Agaricus bisporus, Pleurotus tuber-regium, Amanita phalaoides and Amanita verosa were collected from eleven locations in Uke, Abatete, Ideani, Nnobi, Nnewi (Okpuno-egbu), Nnewi (Umudim) and Ozubulu between 2009 and 2012 in Anambra State, Nigeria. They were kept in clean collection bags and identified by a taxonomist. Some of the mushroom samples were later oven dried at 75 0 C for 4 hours and kept for chemical analysis while some...
ABSTRACT The azo-ligand, 1,5-dimethyl-2-phenyl-4-[(E)-(2,3,4-trihydroxylphenyl) diazenyl]- 1,2-dihydro-3H-pyrazol-3-one (H3L) and its Zn(II) and Cd(II) complexes have been synthesized and characterized based on stoichiometric, molar conductance, electronic and infra-red spectral studies. The results showed that H3L reacted with the metals in 2:1 ratio. H3L coordination was through the hydroxyl, azo and carbonyl groups to form [Zn(H2L)2] 2+ and [Cd(H2L)2] 2+ respectively. Solvent extraction s...
Abstract The pollution of rivers and lakes by n~tural and human activities is causing some concern thc world over because of the problems it poses to mankind's existence 2 (~epple, ,973'; Hakanson, 1974 ; Bryce-jmitl , 1975~; 4 Hodges, 1977 ; Sada et al, 1%a5, Faculty of Law, 6 University of Ibadan 1988 , His Holiness, Pcpe John Paul XI, 1 9w7). Industrial wheels and products, natural disasters such as floods, explosions and earthqunkcs 1 we continued to pollute the environment including rive...
ABSTRACT Physicochemical and bacteriological analyses of borehole water samples were randomly collected from ten boreholes that supply drinking water to various communities of Aninri, Awgu and Oji River Local Government Areas of Enugu, Nigeria. The boreholes were sampled in both dry and rainy seasons. The following physicochemical parameters: pH, temperature, colour, electrical conductivity, turbidity, total dissolved solids, hardness, calcium, magnesium, sodium, potassium, alkalinity, acidi...
ABSTRACT The composition and bleaching properties of Nteje clay in comparison with two commercially available adsorbents (activated carbon and fuller’s earth) were investigated to study its competence for use as an alternative to high cost imported adsorbents. The modification of the raw clay sample was carried out by acid activation to enhance the surface area of the clay by exchange of octahedral cations e.g Al3+, Fe3+ and Mg2+ with H+ ions which led to the modification of the clay cryst...