Ammonia synthesis is the most important step for nitrogen-fertilizer production and consumes approximately 1% of the world’s energy production and energy-related greenhouse gas emissions. In addition to the concomitant emissions caused by ammonia and nitrogen fertilizer synthesis, centrally produced fertilizer that must be distributed to farms also harms the environment because of the embodied energy of transportation. An environmentally-optimal nitrogen fertilizer system would be distribut...
As the number of prosumer printers has expanded rapidly, they now make up the majority of the 3-D printer market and of these printers those in the open-source lineage of the RepRap also have expanded to dominate. Although still primarily used for prototyping or hobbyist production of low-value products, the RepRap has the capacity to be used for high-value distributed manufacturing. A recent study found that RepRap printed parts printed in realistic environmental conditions can match and eve...
The opportunity for substantial efficiency enhancements of thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic (PV) cells using plasmonic absorbers requires ultra-thin transparent conducting oxide top electrodes with low resistivity and high transmittances in the visible range of the electromagnetic spectrum. Fabricating ultra-thin indium tin oxide (ITO) films (sub-50 nm) using conventional methods has presented a number of challenges; however, a novel method involving chemic...
A new method of preparing highly conductive ultra-thin indium tin oxide for plasmonic-enhanced thin film solar photovoltaic devices. Abstract Recent numerical modeling of plasmonic metallic nanostructures have shown great potential as a method of light management in thin-film nanodisc-patterned hydrogenated amorphous silicon (a-Si:H) solar photovoltaic (PV) cells. A significant design challenge for such plasmonic-enhanced PV devices is the requirement for ultra-thin transparent conducting oxi...
Studies have been carried out on a-Si:H p-in solar cells and corresponding i-layer films fabricated with and without hydrogen dilution for kinetics with high intensity and 1 sun illuminations. The results show a striking similarity between the kinetics in the fill factors (FF) of the p-in solar cells and the mobility lifetime (µτ) products of the corresponding i layer films. New results are presented on thermal annealing after 10 sun degradation which further substantiate the presence of fa...
The inconsistencies associated with the common simple method of evaluating the quality and stability of hydrogenated amorphous silicon (a-Si:H) materials for solar cell applications from just the magnitude of subgap absorption (a(E)) are addressed in this study. The approach taken in this study is to characterize the entire a(E) spectrum by its derivatives, d[a(E)]/dE. Results are presented and discussed for two a-Si:H thin film materials differing in deposition rate by an order of magnitude,...
This paper outlines the evolution of additive manufacturing technology, culminating in 3D printing, and presents a vision of how this evolution is affecting existing global value chains in production. In particular, we bring up questions about how this new technology can affect the geographic span and density of global value chains. Potentially, wider adoption of this technology has the potential to partially reverse the trend towards global specialization of production systems into elements ...
The relationship between microstructure and properties is not widely assessed in parts produced by additive manufacturing, particularly for aluminum. These relationships can be used by engineers to develop new materials, additive processes, and additively manufactured parts for a variety of applications. Thus, the tensile, compressive, and microstructural properties of common aluminum weld filler alloys (ER1100, ER4043, ER4943, ER4047, and ER5356) were evaluated following gas metal arc weld (...
A number of risks could cause widespread electrical failure, including a series of high-altitude electromagnetic pulses (HEMPs) caused by nuclear weapons, an extreme solar storm, and a coordinated cyber attack. Since modern industry depends on electricity, it is likely there would be a collapse of the functioning of industry and machines in these scenarios. As our current high agricultural productivity depends on industry (e.g. for fertilizers) it has been assumed that there would be mass sta...
Nanosphere lithography (NSL) provides an opportunity for a low-cost and scalable method to optically engineer solar photovoltaic (PV) cells. For PV application, NSL is widely used in rear contact scenarios to excite SPP and/or high order diffractions, however, the top contact scenarios using NSL are rare. In this paper a systematic simulation study is conducted to determine the capability of achieving efficiency enhancement in hydrogenated amorphous silicon (a-Si:H) solar cells using NSL as a...
This study reports on a novel synthesis of pure zinc oxide and both Cu and Ag doped ZnO nanoplates using a simple and lowcost hydrothermal method. The structural and optical properties of the nanoplates were quantified and the materials were tested for antibacterial activity. Xray diffraction revealed the formation of the wurtzite phase of ZnO and scanning and transmission electron microscopy showed the formation of randomly oriented ZnO nanoplates, having thickness less than 80 nm and di...
Although theoretically the patent system is meant to bolster innovation, the current United States Patent and Trademark Office (USPTO) is cumbersome and involves a significant time investment to locate inactive patents less than 20 years old. This article reports on the development of an open source database to find these public domain ideas. First, a search strategy is explained. Then the operation and use of free and open source software are detailed to meet the needs of open hardware innov...
In addition to their low cost and weight, polymer heat exchangers offer good anticorrosion and antifouling properties. In this work, a cost effective air-water polymer heat exchanger made of thin polymer sheets using layer-by-layer line welding with a laser through an additive manufacturing process was fabricated and experimentally tested. The flow channels were made of 150 μm-thick high density polyethylene sheets, which were 15.5 cm wide and 29 cm long. The experimental results show that t...
Alloy development can simplify low-cost gas metal arc weld (GMAW)-based 3-D printing by making it easier to print quality parts with minimal metallurgical or welding experience. Previous work found good properties in aluminum alloys, particularly in the aluminum-silicon 4943 (Al-5.5%Si-0.4%Mg) and 4047 (Al-11.6%Si) alloys. These alloys were easy to print, but could benefit from alloying to increase ductility and to minimize or redistribute porosity. The purpose of this study was to modify 494...
3D printing functional parts with known mechanical properties is challenging using variable open source 3D printers. This study investigates the mechanical properties of 3D printed parts using a commercial open-source 3D printer for a wide range of materials. The samples are tested for tensile strength following ASTM D638. The results are presented and conclusions are drawn about the mechanical properties of various fused filament fabrication materials. The study demonstrates that the tensile...